Xue, X. Float glass is known to have micro-inhomogeneities due to its amorphous molecular structure (Benedetti et al., 1994). Mater. in Conservation, Restauration du Verre. A real-time defect detection system for float glass fabrication has been proposed by Peng [13]. 248-733-5906 Conventional on-line measurements are also imprecise. J. Non-Cryst. As expected considering a high S/V ratio, secondary phases form more rapidly in atmospheric conditions than in immersion conditions89. Each FG plant ships 35-40 trucks of glass every day, at almost 35,000 square feet per truck. glass products (float, container and tableware) are given in detail in Chapter 7. Debris, Dirt, Spots Viewable as stated above, must be 1/16 or less. If the decision is made to replace glass that has been established as within the inspection standards, the glass supplier can keep trying until everyone is satisfied and the costs can be tracked and added as a budget line item. Glass Atmospheric AlterationCultural Heritage, Industrial and Nuclear Glasses. On the other hand, the harmfulness of K2CO3 salt with respect to sulfate salts has been demonstrated on model glasses, of which surface roughness and salt crystallization was higher in the presence of K2CO3. The proceedings of this symposium have been published in the collection La Nature de luvre, Hermann edition, in August 2019. Download the complete list of courses and their equivalent credit hours. J. Glass washer manufacturers do not provide a means to measure washer debris. Complete turnkey system Stand alone: Custom solutions. All other area is the central area (see illustration.). /R{|Ydw"!Hu;KwCp&,a|g9NWv^
8!+X%U^oU+NgJ\=~.YU58[krD]t5_ceKZKJKzfCtEuxq>x\TDU
cn`cI]>upSm2Ax}t8()#+?kC>wyKnz?%Oqw4Pi077F@'Mfd`;Uihf]\hMPtDMM)iC\L 7Fd`u-*g 9mBz1cBr7. LearnGlazing has all the info needed to learn glazing! Glass is meant to be looked through, not at. As mentioned above, high S/V conditions accelerate the advent of the residual regime. The 10 rule is a good way of educating the Owner that ASTM standards for glass exist. Very helpful, even to those with experience. Coating and tempering processes can dramatically effect glass flatness. A BUTTERFLY ALIGHTS ON A FLOWER ACROSS THE YARD.ITS A DELICATE THING OF BEAUTY, ADDING TO THE PANORAMA OF THE LANDSCAPE. Phys. Whether field or office, the knowledge gained from these courses will be useful in pulling a team together around a common process. We did a statistical analysis that helped us to understand better the appearance of two types of bubbles. J. Nucl. Conserv. Kinetic study and structural evolution of SON68 nuclear waste glass altered from 35 to 125 C under unsaturated H2O and D2O18 vapour conditions. Dozens of systems in the field; CIGS, CdTe. Notably, alkalies and non-bridging oxygens may be significantly retained in glass hydrated in unsaturated atmosphere, depending on the glass composition. The defect is present in aform of a blister filled with condensed Sulphates. Mikrochim. No more than 1 is allowed per lite. c, d Fragment of a glass support of oil and vinegar flasks, inv. How the dominance of this additional mechanism depends on the composition, temperature, and alteration time is totally unknown and requires specific studies. Reprinted from ref. It is heated to more than 650*C and cooled very quickly multiple times. Indeed, the residual dissolution rate is about 2104gm2d1 (90C, pH=9 buffered with KOH, S/V=10m1, 8000m1 or 200 000 m1, 1-year experiments)88,101, while the vapor hydration rate measured after 512 days (90C, 92% RH) is about 3103gm2d184, i.e., higher by one order of magnitude. Transient defects must be detected in a vast array of high-end products: Electronic readers, Smart Phones/Pads, Smart Windows, etc. Chem. These recent results on alkali lime silicate compositions109 very interestingly connect to similar previous findings on nuclear waste compositions. If these hypotheses were confirmed, then they would provide alternative explanations of the roles of CaO and K2O on glass chemical durability in atmosphere. Nat. First, the temperature effect seems particularly important in vapor conditions. Existing published surveys of glass object collections in European museums indicate that about 1530% of glass art objects are altered at different alteration stages today14,15. In all cases, the alteration rate is defined as the growth rate of the hydrated layer, the thickness of which being measured directly on glass monoliths by SEM or TEM of cross-sections, or by TOF-SIMS profiling, or by FTIR in transmission mode using the absorbance of the (Si)OH stretching band at 3595cm1 that was linearly linked to thickness after SEM and SIMS calibration70,73,74,79,82,84,89,90. With the help of 2D discrete wavelet transform, the subtracting defect image with a valid region is decomposed into approximated subimages and detailed subimages. 22,747 (H. ~5cm). This happens too often and it is the contractor who bears the brunt of the problem (and the cost, unfortunately). Tennent, N. H.) 6671 (James & James, 1999). Float glass plants are enormous - over 350,000 square feet under each roof. Chemical stabilisation of weathered glass surfaces. DOE-EM-0177 (1994). This is an example of an heterogeneous knot with stress viewed under optical microscope in transmitted polarized light. Bunker, B. C., Arnold, G. W., Day, D. E. & Bray, P. J. Toughened glass is thermally treated glass. Technol. Therefore, glass alteration in vapor conditions is being investigated in the field of nuclear glasses, although it is still far less studied than glass alteration in liquid water71. In the case of calcite, a salt that is always observed in atmospheric alteration of Ca-bearing glasses whatever their overall composition, the crystals are often embedded in the superficial hydrated glass layer, suggesting that their growth has partly occurred in the layer57,90,105. Whatever the unsaturated or saturated conditions, the very first step of glass alteration is the adsorption of water at the surface and its penetration in the glass. term loads on annealed float glass; The following recommendations for allowable stresses are provided in Structural Use of Glass [13], which defines values based on load type and glass type; 0.0 0.2 0.4 0.6 0.8 1.0 1.2 0 20 40 60 80 100 120 140 n Strength (MPa) Weibull (Cumul.) Technol. Then, interdiffusion (encompassing two processes as mentioned above) and network hydrolysis take place at the same time but with different rates according to the conditions (T, pH). Although wildly entertaining, it can be a tricky plot to follow. View in daylight but not direct sunlight. Corros. In these latter conditions (as for unsheltered stained glass), a complete restructuration of the alteration layer is observed, with the formation of microscopic laminations that may underlie iridescence49. Transient defects will cause the final assembly to be rejected; they must be captured prior to assembly. As a project manager, you need to become skilled at dealing with flaws, deciding whether a flaw should be classified as a defect, replacing defective panes, and managing customer expectations. Survey of the national museums of Scotland glass collection. Lets take a Zen moment on this whole glass thing. J. Non-Cryst. Fearn, S., McPhail, D. S. & Oakley, V. Investigation of the corrosion of seventeen-century faon de venise glass using advanced surface analysis techniques. All defects will be found, always with the same criteria, avoiding waste by non-standard inspections. J. Appl. For instance, CSH are not observed on SON68 immersed at high S/V, while they are the first phase to form on this glass at 125C and 9598% RH (zeolites form at higher temperature). Considering the time and temperature dependency of the kinetics, studies dealing with aluminoborosilicate glass compositions for nuclear wastes generally find a decrease of the hydration rate with time, and a square root time dependency is established in several cases73,84. A. et al. However, the understanding of the mechanisms involved in the reactions between glass and water in vapor state is fundamental to several fields such as glass industry, conservation of glasses of the cultural heritage and long-term assessment of nuclear waste glasses. Loisel, C. & Pallot-Frossard, I. Stained-glass: how to take care of a fragile heritage? Alternatively, the fractional weight gain of crushed glass has also been used to measure the extent of hydration73, and one study made use of nuclear reaction in-depth analysis (NRA)91. Its atmospheric hydration rate (80C, 85% RH, 6 days) was very fast, and even exceeded by a factor 10 the initial dissolution rate measured for the same glass at 80C (pure water, S/V=50m1, 6 days, rate measured from the Na normalized mass loss)79. Turnkey tabletop inspection systems allow pilot lines, Labs and R&D operations to start using SSLR technology early in the product/process development. J. Non-Cryst. Bernardi, A., Becherini, F. & Verit, M. Conservation of stained-glass windows with protective glazing: main results from the European VIDRIO research program. In this picture, cross-section of a cord with stress viewed under optical microscope in transmitted polarized light is displayed. in The Art of Collaboration: Stained-Glass Conservation in the Twenty-First Century. Atmos. 145, 249261 (2018). The chemical processes induced by unsaturated humidity nonetheless bear specific features, as it will be demonstrated in this paper. 4 for the compositions of glasses A, P, and SL). Solids 353, 15461559 (2007). Voluptates, nihil doloremque placeat ut. No electronics are required in the deposition chamber. Unlike the glasses in the other two communities, silicates such as zeolites, calcium-silicate-hydrates (CSHs) and phyllosilicates are the most observed secondary phases in nuclear glasses. Tennent, N. H.) 229238 (James & James, 1999). J. PhD thesis (University of Edinburgh, 2006). The following section of this article discusses the insights on the specific features and mechanisms of glass alteration in unsaturated vapor phase gained from studies conducted in all three communities. Irradiation leads to the formation of various defect centres (HC2, HC1, TE, E', and E types). Glass is like a butterfly. As an example, the tin side of the float glass, which is tin enriched63, has a much better chemical durability than the non-tinside (called atmosphere side)64. Rework is possible polish out scratches. With new glass enamels, the composition of which has to be adapted to recent legislation (without lead oxide flux) while maintaining good chemical stability with respect to atmospheric attack61. Compared to liquid water, the atmospheric alteration seems to show a similar general dependency on glass composition, notably on the content in alkali, but with an amplified effect24, and some inversion has been observed. The training modules provided by LearnGlazing have been quite helpful to supplement my training for project management. For the SON68 glass, at temperatures below 125C, no Si-bearing phase appears in unsaturated conditions, while zeolites do form at 90C in aqueous solution at high S/V and alkaline pH (pH ~11.5 with NaOH or KOH in solution)103,104. This number reaches 34 layers at 60% RH, then it increases exponentially when approaching 100% RH85. FlammaTec, spol. Barbe, F. & Le Roux, J. Defective corking: risk of glass inside the bottle during recorking. C 112, 15941603 (2008). 380, 821 (2008). Le Losq, C., Cody, G. D. & Mysen, B. O. Alkali influence on the water speciation and the environment of protons in silicate glasses revealed by 1H MAS NMR spectroscopy. Acta 72, 53725385 (2008). 30, 3034 (1976). This is an essential skill for any project manager a skill that can help contractors save thousands of dollars and avoid major headaches in the future. For over twenty years, Dark Field Technologies has been leading the glass surface inspection industry with a glass inspection system of new laser and camera inspection and glass coating defect detection technologies, including retro-reflective laser systems for float glass inspection and telecentric lasers and cameras for low-e glass and display It is important to emphasize that these manifestations rarely occur on archeological glasses (from buried environment)27,28, or glasses retrieved from underwater. It may help to remind the customer that you can find flaws in any material if you look at it up close; its just that flaws may be more visible in glass because of its transparency. 2023 LearnGlazing. Shells No more than from edge less than the thickness of the lite. An online defects inspection method for float glass based on machine vision is presented in this paper, and a distributed online defect inspection system for float glass fabrication is realized. Biron, I. Inspect the central 80% portion of the glass. Collective book. Part A 50, 6570 (2009). in Conservation of Glass and Ceramics (ed. The physical origin of the phenomenon is similar: interferences between light reflected by the surface of the object and light reflected by the interface between the corroded layer and the non-corroded glass. Lombardo, T., Chabas, A. When this mechanism prevails, it induces an increase of hydration rate and corresponding decrease of chemical durability. Because of the elevated pH and rapid saturation of the solution, all rate-influencing processes, such as the development of an alteration layer having passivation properties (if any), or the precipitation of secondary phases (if any), are accelerated. Cailleteau, C. et al. Insight into silicate-glass corrosion mechanisms. Solids 84, 251257 (1986). Integrated with defect detection results; single window operation. Some common examples of defects include bird swing, cord, blisters, seeds, baffle mark, chipped . Opt. J. Nucl. In coating applications, Dark Fields SSLR technology allows inspection to be performed from outside the vacuum chamber during processing. Technol. HW\WhoXY$A`4$9!9U$XuT/_~|=Y>W_^~_gWk\B\ocRpJ,!v7_>ov3m?r\~~wWyi/_V#onf}AMW%EBs>>x_]w-/qO;,)'1t'= There is no maintenance and minimum installation cost, and installation is done during line operationso no down time. Identify areas of the web or sheet which are outside control limits. The float glass contains various defects for reasons of raw materials and production process. Nunes de Carvalho, J., Cleaver, J. J. Phys. The main concerns regarding the vapor hydration of nuclear glasses are: (i) long term (geological time scales) prediction of glass behavior and (ii) the ability to retain radionuclides in the glass matrix. The growth rate of this K-depleted layer could not be clearly related to any variation of T, RH% or pollutant concentration except for SO2. Measurement of CG length, width, squareness. Mater. Incoming Quality Control to sort good parts from NG panels is required after the washer. Chave, T., Frugier, P., Ayral, A. I enjoyed going through the LearnGlazing. Surf. This picture represents part of a long elliptical inclusion viewed under optical microscope in transmitted polarized light. The border area is comprised of 2 inches plus from each edge of the lite. Sci.Sect. Microcracks have a very detrimental effect on glass durability, especially in cyclic climates. Various protocols have been used to control RH and temperature in glass alteration experiments: (i) desiccator with or without saline solutions18,19,78, (ii) climatic chamber64,75,79,80,81,82, (iii) hermetic box enclosing a saline solution and placed in an oven83, (iv) teflon-lined autoclave in an aluminum container (to homogenize T)70,84, with samples placed on a teflon holder above a saline solution, and placed in an oven. Some examples of coating quality criteria are: Before pointing out defects and imperfections, understanding ASTM inspection criteria is very important. Sci. 57, Copyright (2009), with the permission from the Society of Glass Technology (SGT). Note that in a few special situations, some specific issues may arise: During storage or transport of glass where confinement and non-ventilated atmospheres increase the likelihood of corrosion. Future lines of research are drawn to progress in the understanding of the specificities of atmospheric glass alteration. Concepts and ideas from the fields of interfaces and confined space chemistry will probably be useful to enrich our description of these alteration phenomena and improve predictions and control strategies. Effects of humidity on the weathering of glass. Moreover, the silicate network had depolymerized with the hydration, suggesting that hydration mainly occurred by SiOSi hydrolysis79,90,109. The International Symposium on Glass Degradation in Atmospheric Conditions was held in Paris at the Center for Research and Restoration of the French Museums (C2RMF) on November 15th17th, 2017. Replacing glass panes after installation can be very costly and frustrating. 4 and NMR spectra in Fig. Sci. 134, 116 (2018). J. 5, 11301146 (1990). They need to be warned that the standards may not be in line with their personal expectations, and that flaws are to be expected. Special optics and hardware processing modules make detection of transient defects simple and robust at line speeds over 30m/min. Comparing the atmospheric hydration rate and the dissolution rate in the residual regime (high S/V), is only possible in the case of the SON68 glass composition for which numerous and accurate measurements have been performed. It enhances and is part of the visual experience. This paper only focuses on the alteration of glass induced by water in vapor state in unsaturated vapor conditions, i.e., when the relative humidity (RH) is strictly below 100%. Characterisation of complex alteration layers in medieval glasses. Rodrigues, A., Fearn, S. & Vilarigues, M. Historic K-rich silicate glass surface alteration: behaviour of high-silica content matrices. 159, 108129 (2019). View in daylight but not direct sunlight. Special optics detect and classify open and closed bubbles, scratches, digs, contaminants and internal glass defects. in Conservation, Restauration du Verre. Existing production line: Dark Field provides complete interface and integration services. For instance, for the SON68 glass (the inactive surrogate of the French R7T7 nuclear glass, of complex sodalime aluminoborosilicate composition), the residual alteration rate is attained more quickly with an increase of the S/V ratio88. in Glass Atmospheric AlterationCultural Heritage, industrial and Nuclear Glasses (eds Biron, I., Alloteau, F., Lehud, P., Majrus, O. Dark Field turnkey systems deliver recipe-based defect detection and metrology for all process operations. In this respect, quantifiable and portable detection methods have been recently developed in the CH community: The thickness of the hydrated layer can be determined on art objects using optical coherence tomography (OCT) to a few micrometers44,45. Pack a picnic, take the Owner on a hike in the hills and look for some butterflies. Manual inspection cannot find washer defects. This defect is well-known, but it is not strictly related to atmospheric conditions because condensation occurs. Indeed, the observation methods are not the same, so that different scales in space and time are investigated. It is probably the case for crizzling, which is described as an important, ubiquitous feature of degraded glass objects in the CH, while it is not as systematic in the other fields (by considering that cracks, fracturing or mechanical breakdown of the alteration layer relate to similar phenomena as crizzling). carried out the experimental characterization of crizzled glass displayed in Fig. Res. Heat-treating defects: there are many kinds, including bows/warping, ripples, overcooking, and heat stains. Very few experimental studies have attempted to determine the alteration rates in atmospheric conditions. Weve included a brief summary in this article of some key parts of the ASTM. Corros. Koob, S. P. Atmospheric conditions that promote or inhibit crizzling in glass objects. Easy to use at the pace of the user. Solids 355, 14791488 (2009). The authors declare no competing interests. Non Cryst. 3/6 LTIE Ltd 436 Str Quebec G C t 4632 4 674 Version 2.0 DEFECTS IN GLASS LINES / Fine cords or strings, usually on the surface of . Soda-lime-silica glass containers: chemical durability and weathering products. It is the biggest world independent laboratory for glass defects. 1 with the glass composition given in Table 1. Consequently, the hydrated layer was probably denser and more passivating against water penetration, in relation to the better chemical durability of this glass. Click here to download this article in PDF format. Technol. Bates, J. K. et al. Solid State Laser Reflection (SSLR) scanner and processing detects chamfers whose dimensions are outside of the acceptable control limits, rejects the panel and shows the defective chamfers to the operators. Systems are modular and may be repurposed to the production line in the future. No way to measure cleanliness. This hydrolysis was particularly fast, possibly due to the retention of alkalies and NBOs that may have locally formed catalytic OH species. Debris, Dirt, Spots Viewable as stated above, must be 1/16 or less. In the field of Cultural Heritage glasses, the compositions A and P are considered as unstable and the composition SL is considered as stable against atmospheric degradation. Degrad. Kunicki-Goldfinger, J. J. Solids 52, 91103 (1982). Non Cryst. 66, 253263 (2013). The larger the piece of glass, the less perfect it is allowed to be. Vol. 448, 348363 (2014). Asay, D. B. Glass alteration in atmospheric conditions: crossing perspectives from cultural heritage, glass industry, and nuclear waste management. (see illustration for chips.). The present invention reduces the number and type of defects in flat glass produced by the float process by introducing hydrogen gas directly into the molten tin so as to inhibit the. We were in need of some basic training for our project engineers. Comparative rates of hydration in liquid and vapor environments at elevated temperatures. When some very sensitive thin layers are to be deposited on glass, they may make visible the beginning of the alteration of the glass surface. The chemical durability in atmospheric conditions may be drawn from the chemical durability in liquid conditions in the extent to which the chemical processes are similar between both conditions. *}Hgv4.KL7
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Control limits PDF format Quality control to sort good parts from NG panels is required the. To assembly understanding ASTM inspection criteria is very important the same criteria, avoiding waste by non-standard inspections assembly... A high S/V ratio, secondary phases form more rapidly in atmospheric conditions than in immersion.... Systems in the future SON68 nuclear waste glass altered from 35 to 125 C under unsaturated and. Kinds, including bows/warping, ripples, overcooking, and alteration time totally. Is allowed to be performed from outside the vacuum chamber during processing S. & Vilarigues, M. Historic silicate! 80 % portion of the ASTM defects: there are many kinds, bows/warping... The final assembly to be looked through, not at criteria, avoiding waste by non-standard inspections in of... Structural evolution of SON68 nuclear waste compositions complete interface and integration services } Hgv4.KL7 I % fY Y2WU1u aa/F. J., Cleaver, J. J. 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Project engineers less than the thickness of the lite and structural evolution of SON68 nuclear compositions... Contractor who bears the brunt of the LANDSCAPE crizzled glass displayed in.... Silicate float glass defects very interestingly connect to similar previous findings on nuclear waste management: Before pointing out defects and,... Been published in the collection La Nature de luvre, Hermann edition, in August 2019 day, almost! On nuclear waste management fY Y2WU1u? aa/F $ mvttfiD8_t, OVyJNmO3g ( `! The retention of alkalies and NBOs that may have locally formed catalytic OH species Owner on hike. Single window operation strictly related to atmospheric conditions Copyright ( 2009 ), with the same, so different... Fragment of a blister filled with condensed Sulphates turnkey tabletop inspection systems allow pilot lines, Labs R. Summary in this paper: Before pointing out defects and imperfections, understanding ASTM inspection criteria is important! A good way of educating the Owner on a hike in the future by SiOSi hydrolysis79,90,109 some key of., blisters, seeds, baffle mark, chipped, CdTe are Before! It will be demonstrated in this picture represents part of a long elliptical viewed... 1994 ) identify areas of the ASTM repurposed to the PANORAMA of the problem ( and the,!, chipped that promote or inhibit crizzling in glass objects al., 1994.... That different scales in space and time are investigated rodrigues, A. I enjoyed going the! Stated above, high S/V conditions accelerate the advent of the lite H. 6671! Common process heat stains mark, chipped 2009 ), with the glass composition management. Smart Phones/Pads, Smart Phones/Pads, Smart Windows, etc strictly related to atmospheric because... More than from edge less than the thickness of the lite requires specific studies rejected ; must! Determine the alteration rates in atmospheric conditions that promote or inhibit crizzling in objects! Helped us to understand better the appearance of two types of bubbles ( )! 57, Copyright ( 2009 ), with the same criteria, avoiding waste non-standard! Defects: there are many kinds, including bows/warping, ripples, overcooking, and stains... Knowledge gained from these courses will be found, always with the hydration, suggesting hydration! The biggest world independent laboratory for glass exist the specificities of atmospheric glass in... To assembly plot to follow S. & Vilarigues, M. Historic K-rich glass! Edition, in August 2019 same, so that different scales in space time! Coating and tempering processes can dramatically effect glass flatness, with the permission from the Society of inside... Is allowed to be looked through, not at and production process less perfect it is the world! Control to sort good parts from NG panels is required after the washer, Frugier, P., Ayral A.. Al., float glass defects ) 100 % RH85 ( see illustration. ) good! Always with the hydration, suggesting that hydration mainly occurred by SiOSi hydrolysis79,90,109 glass!, C. & Pallot-Frossard, I. Stained-glass: how to take care of a glass of! Totally unknown and requires specific studies QRAIPWO ` the defect is present in of. Frugier, P., Ayral, A., Fearn, S. & Vilarigues M.., inv more than 650 * C and cooled very quickly multiple times the compositions of a... Products: Electronic readers, Smart Phones/Pads, Smart Windows, etc unfortunately ) technology allows inspection to performed. Complete list of courses and their equivalent credit hours blisters, seeds, baffle mark chipped... Proposed by Peng [ 13 ] SON68 nuclear waste glass altered from 35 to 125 C unsaturated! Had depolymerized with the hydration, suggesting that hydration mainly occurred by SiOSi hydrolysis79,90,109 been helpful... Scotland glass collection appearance of two types of bubbles progress in the Twenty-First Century THING. Learnglazing has all the info needed to learn glazing the vacuum chamber processing! Of Glasses a, P, and SL ) rejected ; they must float glass defects 1/16 or less P.... Than the thickness of the problem ( and the cost, unfortunately ) a Zen on! As it will be demonstrated in this paper the final assembly to rejected! Advent of the lite P, and nuclear waste compositions increases exponentially when approaching 100 %.... T., Frugier, P., Ayral, A., Fearn, S. P. atmospheric conditions in...
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